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Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
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Published on: November 30, 2022

主鎖のボロン含有オリゴフェニレンは,9-H-9-ボラフッロレンのリング開きポリメリゼーションによる

Alexander Hübner1, Zheng-Wang Qu, Ulli Englert

  • 1Institut für Anorganische und Analytische Chemie, Johann Wolfgang Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, D-60438 Frankfurt am Main, Germany.

Journal of the American Chemical Society
|March 4, 2011
PubMed
まとめ

9-H-9-ボラフルオレン (5) は,in situ生成によってユニークな二元およびオリゴマーを形成する. これらの構造は,B-H-B結合とボロン橋渡しフェニル環を特徴として,NMRとX線結晶学によって特徴付けられています.

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