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Updated: Jun 3, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

Pd触媒による酸化クロスカップリング反応における制御部位選択性を制御する

Thomas W Lyons1, Kami L Hull, Melanie S Sanford

  • 1Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.

Journal of the American Chemical Society
|March 9, 2011
PubMed
まとめ

この研究では,キノンのプロモーターとカルボキシラートリガンドが,パラジアム触媒による酸化結合反応におけるサイト選択性を制御する方法を明らかにした. リガンド置換は選択性を逆転させ,アレン機能化のための新しい合成制御を提供します.

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