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Updated: Jun 3, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

グアニジニウム触媒によるエナチオセレクティブ・クライスン再配列における複数の非共性相互作用による移行状態の電荷安定化

Christopher Uyeda1, Eric N Jacobsen

  • 1Department of Chemistry & Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA.

Journal of the American Chemical Society
|March 12, 2011
PubMed
まとめ

チラルのグアニジニウム触媒は,水素結合とπ-カチオン相互作用を通じて,クライゼン再配列をエナチオ選択的に促進する. このメカニズム的理解に基づいて,改善されたエナチオ選択性を持つ新しい触媒が開発されました.

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