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Updated: Jun 3, 2026

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
07:30

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

Published on: January 21, 2020

Rh2 (((II) 触媒によるニトログループ移行反応: β-ニトロステリルアジドから3ニトロインドルを選択的に合成する

Benjamin J Stokes1, Sheng Liu, Tom G Driver

  • 1Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061, USA.

Journal of the American Chemical Society
|March 16, 2011
PubMed
まとめ

ロジウム触媒は,ステリルアジドの電子取り除く群移動を促進し,3-置換インドールを生成します. この反応は,有価なインドール誘導体への選択的な経路を提供します.

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