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Updated: Jun 3, 2026

Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
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Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile

Published on: October 30, 2018

2つの異なるアルデヒドを,クロスカップリングされたエステルに,ニッケル触媒で選択的に変換する

Yoichi Hoshimoto1, Masato Ohashi, Sensuke Ogoshi

  • 1Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.

Journal of the American Chemical Society
|March 17, 2011
PubMed
まとめ

新しいニッケル触媒反応により,アリファ酸アルデヒドとアリルアルデヒドの選択的クロスカップリングを単一のエステルに可能にします. この100%の原子効率の良いプロセスは,廃棄物を発生させず,同時に二重アルデヒドの調整をNi(0) に示します.

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