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Updated: Jun 3, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

高スピンの鉄イミド複合体からの触媒C-H結合アミナーション

Evan R King1, Elisabeth T Hennessy, Theodore A Betley

  • 1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.

Journal of the American Chemical Society
|March 17, 2011
PubMed
まとめ

巨大な二ピロメタンリガンドを持つ新しい鉄複合体は,C-Hアミネーションとオレフィンアジリジネーションを触媒化する. 高スピンの鉄 (III) イミドラジカルの中間物質が特定され,これらの反応における触媒活性が説明されました.

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