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Updated: Jun 2, 2026

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
10:17

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones

Published on: February 7, 2019

エアロビック Pd-触媒 sp3 C-H オレフィネーション: N-ヘテロサイクリック・スキャフォールドとアルケーンの両方への経路

Kara J Stowers1, Kevin C Fortner, Melanie S Sanford

  • 1Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.

Journal of the American Chemical Society
|April 12, 2011
PubMed
まとめ

新しいパラジウム/ポリオキシメタラート法により,窒素ヘテロサイクルの使用により,C−H結合の有酸素オレフィネーションが可能になる. このアプローチは,過度の機能化を防止し,さらなる合成のための貴重なバイサイクリック・スキャフォルドとオレフィンを生成します.

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Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

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