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Updated: Jun 2, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

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Published on: October 3, 2014

OMPデカルボキシラーゼ:フォスフォディアニオン結合エネルギーは,ヴィニルカルバニオン中間体を安定させるために使用されます

Bogdana Goryanova1, Tina L Amyes, John A Gerlt

  • 1Department of Chemistry, University at Buffalo, Buffalo, New York 14260, USA.

Journal of the American Chemical Society
|April 14, 2011
PubMed
まとめ

オロチジン5'-モノフォスファートデカルボキシラーゼ (OMPDC) は,フッ素ウラシルの類似体でデウテリウム交換を容易にする. Fosphite dianionは,過渡状態を著しく安定させ,酵素反応におけるその役割を明らかにします.

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