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Updated: Jun 2, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Published on: June 24, 2022

N-ヘテロサイクルの化合物のイリジウム触媒化水素化は,外球経路による温和な条件下で行われる

Graham E Dobereiner1, Ainara Nova, Nathan D Schley

  • 1Department of Chemistry, Yale University, 225 Prospect Street, P.O. Box 208107, New Haven, Connecticut 06520, USA.

Journal of the American Chemical Society
|April 23, 2011
PubMed
まとめ

新しいイリジウム触媒は,穏やかな条件 (25 °C,1 atm H2) でキノリンの水素化を可能にします. この研究は,この重要な化学的変換のための異常な外界のメカニズムを明らかにしています.

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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