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Updated: Jun 2, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
11:45

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

アザ-オキシアリルカチオンの中間物質の生成と反応性:ヘテロサイクルの合成のためのアザ-[4 + 3]サイクロアディション反応

Christopher S Jeffrey1, Korry L Barnes, John A Eickhoff

  • 1Department of Chemistry, University of Nevada-Reno, Reno, Nevada 89557, USA. cjeffrey@unr.edu

Journal of the American Chemical Society
|May 4, 2011
PubMed
まとめ

この研究では,α-ハロアミドから生成されたアザ-オキシアリルカチオン中介物質を用いたaza- [4 + 3] サイクル添加について詳細に説明しています. この反応はダイアステレオセレクティブであり,一般に適用され,N-アルコキシ群が中間安定性を高めます.

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