不活性化された二次アルキル塩化物によるステレオコンバーゲントアミン誘導アルキルアルキルスズキ反応

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Updated: Jun 2, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

Zhe Lu1, Ashraf Wilsily, Gregory C Fu

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|May 11, 2011
PubMed
まとめ

研究者らは,スズキ反応で活性化されていないアルキル塩化物を用いた新しいステレオコンバージェントクロスカップリング方法を開発した. このアリラミンによるアプローチは,アルキル-アルキル結合の形成を効率的に可能にし,非対称な触媒を推進します.

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