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Updated: Jun 2, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

削除可能なシリル群を使用したマクロサイクリック環閉メタテシスのオレフィン幾何学の制御

Yikai Wang1, Miguel Jimenez, Anders S Hansen

  • 1Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA.

Journal of the American Chemical Society
|May 12, 2011
PubMed
まとめ

シリル基を二olefinic 基板に導入することは,マクロサイクルのリング閉じるメタテシス中にE選択的オレフィン形成を誘導します. その後シリル基の除去により,Z構成のマクロサイクルにアクセスでき,合成の可能性が広がります.

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