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Updated: Jun 1, 2026

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction
12:22

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

Published on: February 4, 2013

SmI2の反応における触媒Ni (II) 反応: Sm (II) -またはNi (0) ベースの化学反応

Kimberly A Choquette1, Dhandapani V Sadasivam, Robert A Flowers

  • 1Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, USA.

Journal of the American Chemical Society
|May 31, 2011
PubMed
まとめ

触媒ニッケル (((II) 塩は,ニッケル (((0) に還元することによって,サマリウムバービエの反応を強化する. このニッケル ((0) は,酸化添加による反応を駆動し,この過程の基礎にある既知のニッケル化学を明らかにします.

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