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Updated: Jun 1, 2026

Monitoring the Reductive and Oxidative Half-Reactions of a Flavin-Dependent Monooxygenase using Stopped-Flow Spectrophotometry
12:08

Monitoring the Reductive and Oxidative Half-Reactions of a Flavin-Dependent Monooxygenase using Stopped-Flow Spectrophotometry

Published on: March 18, 2012

ディメチルスルフォキシド還元酵素の触媒介質の光譜および電子構造の研究:電子および原子移転反応性への影響

Regina P Mtei1, Ganna Lyashenko, Benjamin Stein

  • 1Department of Chemistry and Chemical Biology, The University of New Mexico, MSC03 2060, 1 University of New Mexico, Albuquerque, New Mexico 87131-0001, USA.

Journal of the American Chemical Society
|June 9, 2011
PubMed
まとめ

研究者らは,EPR,電子吸収,MCD光譜を用いて,ジメチル硫酸化還元酵素 (DMSOR) のパラマグネット性デソキシモウソウ (Mo(V) 中間物質の電子構造を調査した. 発見により,低対称性の幾何学と金属中心の軌道が明らかにされ,酵素の機能にとって極めて重要です.

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Preparation and Reactions of Sulfides

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