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Updated: Jun 1, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

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メチルヒドロキシカルベン:化学反応のトンネリング制御

Peter R Schreiner1, Hans Peter Reisenauer, David Ley

  • 1Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany. prs@org.chemie.uni-giessen.de

Science (New York, N.Y.)
|June 11, 2011
PubMed
まとめ

量子力学的トンネリングにより,反応は従来の運動制御を回避し,より高いエネルギー経路を通る製品を好むことができる. この現象は,メチルヒドロキシカルベンのイソメリゼーションで観察され,トンネル掘削を実証しました.

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