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Updated: May 31, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
11:45

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

難解な4つ組のリングアゼテオポルフィリンへのメカニズム的な経路をゲーティングします

David F Dye1, Tillmann Köpke, Raghunath O Ramabhadran

  • 1Department of Chemistry, Indiana University, Bloomington, Indiana 47405, USA.

Journal of the American Chemical Society
|July 2, 2011
PubMed
まとめ

低温での金属化塩素の光分解は,ウォルフ再配列を駆動し,アゼテオポルフィリンを形成する. 室温の反応により,カルベンとケテンの中間産物から様々な製品が得られる.

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