複合C-H機能化/コップ再配列は,ビニルエーテルをビニルロゴスのムカイヤマアルドール反応の代替物として用いる

関連する実験動画

Updated: May 31, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
07:36

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

Yajing Lian1, Huw M L Davies

  • 1Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, USA.

Journal of the American Chemical Society
|July 12, 2011
PubMed
まとめ

チラルディロジウム触媒は,ビニルエーサーをC-H機能化/Cope再配置の組み合わせに耐えるようにします. この高度に選択的な反応は,キラル化合物を合成し,エナティオマーを分解するための新しい経路を提供します.

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[3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement

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Vicinal Diols via Reductive Coupling of Aldehydes or Ketones: Pinacol Coupling Overview

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