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Updated: May 31, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

異質な亜鉛二炭酸塩に対する機械的洞察と,CO2エポキシード共ポリマー化のための理論的考察

Stephan Klaus1, Maximilian W Lehenmeier, Eberhardt Herdtweck

  • 1WACKER-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching bei München, Germany.

Journal of the American Chemical Society
|July 13, 2011
PubMed
まとめ

異質な亜鉛二炭酸塩はエポキシドとCO2の共聚合を触媒とする. この研究は,バイメタリックメカニズムと最適の亜鉛-亜鉛距離を明らかにすることにより,活性性の違いと限界を説明し,触媒設計を改善します.

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