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Updated: May 31, 2026

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
10:17

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones

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1,3-サイクロヘキサディエンのステレオ選択型サイクロアディション (Stereoselective cycloaddition) がSi{100}上に行われている:二次軌道相互作用に基づく製品識別のための単純なアルゴリズム

Peter M Ryan1, Lucile C Teague, David E Meehan

  • 1School of Chemistry and Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2, Ireland.

Journal of the American Chemical Society
|July 13, 2011
PubMed
まとめ

二次軌道相互作用 (SOI) は,熱力学的説明を超えて,Si{100}上の1,3-サイクロヘキサディエンの反応性とステレオ選択性を説明します. この軌道対称性に基づくアプローチは,表面の化学反応を制御するための洞察を提供します.

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