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マスクされた2座標コバルト (I) 複合体で,C−F結合を活性化します

Thomas R Dugan1, Xianru Sun, Elena V Rybak-Akimova

  • 1Department of Chemistry, University of Rochester, Rochester, New York 14627, United States.

Journal of the American Chemical Society
|July 21, 2011
PubMed
まとめ

研究者らは,新しいコバルト複合体,L(tBu) Coを分離し,特徴づけ,それはマスクされた2座標の種として作用することを可能にするユニークなリガンドを特徴付けました. この複合体は低座標コバルト ((I)) の安定シントンであり,炭素-フッ素結合を裂けることができる.

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