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Updated: May 30, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

基板の範囲を拡大し,オルガントリフルオロボラートとアセタルのエーテル形成クロスカップリング反応の反応性が向上しました

Cam-Van T Vo1, T Andrew Mitchell, Jeffrey W Bode

  • 1Laboratorium für Organische Chemie, Department of Chemistry and Applied Biosciences, ETH-Zürich, Switzerland.

Journal of the American Chemical Society
|July 23, 2011
PubMed
まとめ

新しいヒドロキサート脱落基は,アセタールとオルガントリフルオロボラートの交互結合により,ダイアキルエーサーの温和で効率的な合成を可能にします. この方法は,電子欠乏性アリルトリフッ化ボラートを含む様々な基板に対する改良された収穫量と地域選択性を提供します.

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