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Updated: May 30, 2026

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
09:08

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes

Published on: February 27, 2017

活性化されていないオレフィンの分子間移動挿入が,パラジアム-窒素結合に. 移住者の挿入率に対するステリックと電子効果

Patrick S Hanley1, John F Hartwig

  • 1Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801, United States.

Journal of the American Chemical Society
|August 6, 2011
PubMed
まとめ

この研究は,リガンドの性質が,パラジアム-窒素結合へのパラジアム触媒アルケンの挿入にどのように影響するかを明らかにしています. リガンドとアルケンのステリックおよび電子因子は反応速度と産物形成を制御し,触媒機構の洞察を提供します.

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