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Updated: May 30, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

4座標,14電子のRu(II) 複合体: bis(phosphino) シリル結合によって強制された異常な三角形のピラミッド幾何学

Morgan C MacInnis1, Robert McDonald, Michael J Ferguson

  • 1Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada.

Journal of the American Chemical Society
|August 12, 2011
PubMed
まとめ

この研究では,シリコンを含むリガンドによって有効化されたユニークな三角形ピラミッド形幾何学を持つ新しい4座標ルテニウム複合体を報告しています. これらの複合体は,E-H結合の活性化において反応性を示し,低協調性金属種への新たな経路を提供している.

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