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Updated: May 30, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

コバルト ((III)) ベースの触媒システムを使用して,CO2とエピクロロヒドリンの完全な交互の共ポリメリゼーション

Guang-Peng Wu1, Sheng-Hsuan Wei, Wei-Min Ren

  • 1State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, People's Republic of China.

Journal of the American Chemical Society
|August 23, 2011
PubMed
まとめ

この研究は,新しいコバルト触媒を用いて二酸化炭素とエピクロロヒドリンから生物分解性ポリカーボネートの効率的な合成を実証しています. この研究は,電子欠乏エポキシドによる選択的共ポリメリゼーションの課題を強調しています.

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Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of peroxy acids to...
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