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Updated: May 29, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

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2-(3,5-ディニトロフェニル) -1,3-ディシアンカルバニオン: 低エネルギートリプル状態のベンジルアニオン

Raffaele R Perrotta1, Arthur H Winter, William H Coldren

  • 1Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742-2021, United States.

Journal of the American Chemical Society
|August 30, 2011
PubMed
まとめ

電子を取り除くグループを持つベンジルアニオンは,トリプル電子状態を示すことができます. 実験的および計算的研究により,特定のディニトロフェニルディシアンカルバニオンがトリプレートとして存在するか,または低いトリプレート状態を有することを示唆しています.

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