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Updated: May 29, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
10:10

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

Published on: July 28, 2018

末端アルケンの銅で触媒化されたトリフルオロメチル化は,アリルC-H結合の活性化による

Jun Xu1, Yao Fu, Dong-Fen Luo

  • 1Department of Chemistry, Joint Laboratory of Green Synthetic Chemistry, University of Science and Technology of China, Hefei 230026, China.

Journal of the American Chemical Society
|September 15, 2011
PubMed
まとめ

銅の触媒は,C ((sp ((3)) -H活性化による末端アルケンの新しいトリフローロメチル化を可能にします. この反応は,アリルC-H機能化とHeckのような移行状態を含むユニークなメカニズムを提供します.

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