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Updated: May 28, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
08:25

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

Published on: January 17, 2020

非対称な触媒におけるキラルアレンを含むフォスフィン

Feng Cai1, Xiaotao Pu, Xiangbing Qi

  • 1Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75398-9038, United States.

Journal of the American Chemical Society
|October 7, 2011
PubMed
まとめ

塩基群を持つキラルアレンは,移行金属のリガンドとして作用する. Rhodium ((I)) とのアレン・ビスフォシン・リガンドにより,α-ケトエステルにアリルボロン酸を高度にエナンチオセレクティブに添加することができる.

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