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Updated: May 28, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

選択的,分子内アリルC-Hアミネーションのためのダイルテニウム触媒:実験と理論を通じて得られた反応開発と機械的洞察

Mark Edwin Harvey1, Djamaladdin G Musaev, J Du Bois

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.

Journal of the American Chemical Society
|October 11, 2011
PubMed
まとめ

ディルテニウム複合体は,ディルホージウム触媒とは異なり,アリル性C-Hアミネーションを触媒とする. この研究は,選択的なC−H結合酸化のためのダイラジカル中間物質を含む新しいメカニズムを明らかにしています.

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