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Updated: May 28, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
11:45

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

アレニウムイオンの超芳香的安定化:サイクロヘキサおよびサイクロヘプタディエニルカチオン - 実験および計算された安定性およびリング電流

David A Lawlor1, David E Bean, Patrick W Fowler

  • 1School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland.

Journal of the American Chemical Society
|October 20, 2011
PubMed
まとめ

サイクロヘプタディエニルカチオンは,ハイパーアロマ性により,サイクロヘクサディエニル (ベンゼニウム) カチオンよりも著しく安定性が低い. この研究では,安定性の違いを定量化し,ベンゼニウムイオンの安定性に対する置換物の影響を調査します.

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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex10:52

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