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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

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直接メトキシカルボニレーション剤としての活性化金属金

Bingjun Xu1, Robert J Madix, Cynthia M Friend

  • 1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.

Journal of the American Chemical Society
|November 1, 2011
PubMed
まとめ

金属のゴールドは,アルコールとアミンの低温カルボニル化を触媒化し,メトキシカルボニルなどの重要な中間物質を形成します. この環境に害のない方法は,価値ある合成化学物質を生産するためのエネルギー効率の良い代替案を提供します.

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Preparation of Carboxylic Acids: Carboxylation of Grignard Reagents

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Carboxylic Acids to Methylesters: Alkylation using Diazomethane

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Oxidations of Aldehydes and Ketones to Carboxylic Acids

Oxidation of aldehydes and ketones results in the formation of carboxylic acids. Aldehydes, bearing hydrogen next to the carbonyl group, are easily oxidized compared to ketones. This is because an aldehydic proton can easily be abstracted during oxidation.
Aldehydes readily undergo oxidation in strong oxidizing agents such as potassium permanganate and chromic acid. The oxidation can also be carried out using mild oxidizing agents such as silver oxide. In fact, aldehydes can be easily oxidized...
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Properties of Organometallic Compounds

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Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction

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