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Updated: May 27, 2026

Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
05:34

Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes

Published on: December 16, 2019

SO3によるエレクトロフィリックアロマティックサルフォネーション:協調または古典的なS ((E) Arメカニズム?

Gergana Koleva1, Boris Galabov, Jing Kong

  • 1Department of Chemistry, University of Sofia, Sofia 1164, Bulgaria.

Journal of the American Chemical Society
|November 9, 2011
PubMed
まとめ

硫黄三酸化物 (SO3) での芳香的硫化は,特に極性でない溶媒では,1:1のウェランド中間体ではなく,2:1の協調したメカニズムで進行する. この改訂されたメカニズムは計算的にサポートされ,実験の傾向を説明します.

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