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ミックス・バレンスの分子におけるスルー・ボンド対スルー・スペース・カップリング:単一分子スケールでの電子の局所化の観察

Rebecca C Quardokus1, Yuhui Lu, Natalie A Wasio

  • 1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA.

Journal of the American Chemical Society
|December 20, 2011
PubMed
まとめ

スキャニングトンネル顕微鏡では,2つの鉄分子の異なる電子行動が明らかになりました. メタ-Fe2分子は,対称なパラ-Fe2とは異なり,酸化後に非対称な電荷分布を示し,電子結合における分子幾何学の役割を強調した.

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