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Updated: May 26, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
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6つの有機面で構成されたプラトン六面体で, Au クラスターが刻まれている

Masanori Sakamoto1, Daisuke Tanaka, Hironori Tsunoyama

  • 1Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan.

Journal of the American Chemical Society
|December 23, 2011
PubMed
まとめ

研究者は,正方形のポルフィリンを金球に配合することで,ナノ・プラトンの固体を作り出した. この新しい方法により,六面体構造が得られ,ナノマテリアルの設計と自己組み立ての可能性が広がります.

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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