エントロピックの中間物質と隠された速度制限ステップは,表面的に協調したサイクル添加です. 再交配における同位体効果の観測,予測,起源

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Updated: May 26, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
05:51

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

Ollie M Gonzalez-James1, Eugene E Kwan, Daniel A Singleton

  • 1Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842, USA.

Journal of the American Chemical Society
|January 11, 2012
PubMed
まとめ

二塩ロケテンサイクロアディションにおける異常な分子内運動同位体効果 (KIE) は,段階的なメカニズムを示唆している. この発見は,トランジション状態再交差に関連しており,類似の化学反応の洞察を提供します.

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