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Updated: May 25, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

イリウムの触媒によるN-アリルフォスフォラミド酸塩リガンドによるアリルアルキル化反応:範囲とメカニズムの研究

Wen-Bo Liu1, Chao Zheng, Chun-Xiang Zhuo

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, People's Republic of China.

Journal of the American Chemical Society
|February 8, 2012
PubMed
まとめ

新しいN-アリルフォスフォラミドイトリガンドは,非常に選択的なイリジウム触媒によるアリルアルキレーションを可能にします. 機理学的な研究は,C ((sp ((2)) -H結合の活性化を通じて活性なイリダサイクル形態を明らかにし,触媒化学を前進させました.

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Preparation of Alkynes: Alkylation Reaction

Introduction
Alkylation of terminal alkynes with primary alkyl halides in the presence of a strong base like sodium amide is one of the common methods for the synthesis of longer carbon-chain alkynes. For example, treatment of 1-propyne with sodium amide followed by reaction with ethyl bromide yields 2-pentyne.
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Radical Substitution: Allylic Bromination

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Aldehydes and Ketones to Alkenes: Wittig Reaction Overview

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