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Updated: May 25, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

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Pd(III) センターを持つパラマグネティックパラダサイクルは,非対称なアザ-クライセン再配置のための非常に活発な触媒です

Simon H Eitel1, Matthias Bauer, David Schweinfurth

  • 1Institut für Organische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany.

Journal of the American Chemical Society
|February 11, 2012
PubMed
まとめ

非対称的な再配列反応のための最も効果的なパラジウム触媒は,予想外のPd (III) センターを特徴としています. これらの新しいPd(III) コンプレックスは,安定したフェロセンのコアを使用した最初の認識されたエナチオセレクティブ触媒です.

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