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Updated: May 23, 2026

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
08:46

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

Published on: July 26, 2018

3,6-O-(o-キシリレン) ブリッジ付き,軸に富んだグルコシルフッ化物を使用した完全にβ選択的グリコシル化

Yasunori Okada1, Noriaki Asakura, Masafumi Bando

  • 1School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan.

Journal of the American Chemical Society
|April 6, 2012
PubMed
まとめ

この研究は,隣接グループ参加なしに完璧なβ選択性を達成する新しいグリコシル化方法を導入しています. 独特のグリコシルドナーが,軸に富んだ形状に閉じ込められ,効率的でステレオ制御されたグリコシドの合成を可能にします.

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