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Updated: May 23, 2026

The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
12:43

The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique

Published on: November 28, 2016

トライアニオン型Sc3N@I(h) -C80から Sc3N@I(h) -C80メタノ誘導体の電気合成

Fang-Fang Li1, Antonio Rodríguez-Fortea, Ping Peng

  • 1Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968, USA.

Journal of the American Chemical Society
|April 6, 2012
PubMed
まとめ

研究者らは,トライアニオン性スカンジウム窒化物クラスター (Sc(3) N@C(80) を使用して,新しいフルレン誘導体を成功裏に合成しました. この電気合成方法は,以前の試みの限界を克服し,エンドヘドラル金属フルラーネの選択的機能化を可能にします.

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
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