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Updated: May 22, 2026

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Kr/Xeの選択性を,金属・有機構造の温度によって切り替える.

Carlos A Fernandez1, Jian Liu, Praveen K Thallapally

  • 1Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.

Journal of the American Chemical Society
|May 18, 2012
PubMed
まとめ

研究者らは,クリプトン (Kr) とクセノン (Xe) の吸収を,フッ素金属有機フレームワークで研究した. 1つの材料であるFMOFCuは,そのユニークな構造のために0°C以下で異常なKr選択性を示した.

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Crystal Field Theory - Octahedral Complexes02:58

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...