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Updated: May 22, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

カチオンのビスホスフィン一酸化物-パラジウム複合体を用いて機能的なポリオレフィン合成

Brad P Carrow1, Kyoko Nozaki

  • 1Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

Journal of the American Chemical Society
|May 18, 2012
PubMed
まとめ

新しいカチオンパラジウム複合体は,多様な極性モノマーとのエチレン共聚化を可能にし,ランダムな機能群を持つ線形ポリマーを生成します. これにより,機能的なポリオレフィンに対する,既存のフォスフィン-硫酸塩系を超えて,触媒的選択肢が拡大されます.

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