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Updated: May 22, 2026

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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非ペリサイクル反応における芳香的移行状態:アニオン性5エンドサイクルが中止され,シグマトロピクシフトが発生する

Kerry Gilmore1, Mariappan Manoharan, Judy I-Chia Wu

  • 1Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, USA.

Journal of the American Chemical Society
|May 19, 2012
PubMed
まとめ

アロマティック性は,アニオン環の閉塞における移行状態 (TSs) を安定させ,新しい非ペリサイクル反応を明らかにする. この芳香的安定化により,アニオンイソメリゼーションの設計に新たな道が開かれる.

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Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
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[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement

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