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Updated: May 21, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

周期性α-ディアゾカルボニル化合物のRh触媒による分子間反応は,三次性C-H結合移動に対する選択性を持つ

Andrew DeAngelis1, Olga Dmitrenko, Joseph M Fox

  • 1Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA.

Journal of the American Chemical Society
|June 9, 2012
PubMed
まとめ

新しいRh触媒反応は,周期性ダイアゾカルボニル化合物を用いて選択的な分子間変換を可能にします. これらの方法はステリック障害を克服し,サイクロプロパネーションとX-H挿入を様々な基板で容易にします.

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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

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