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Updated: May 21, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

モリブデンとトングストンのモノアリオキシドピロリド (MAP) 複合体による1,3-ディエンのZ選択的メタテシスホモカップリング

Erik M Townsend1, Richard R Schrock, Amir H Hoveyda

  • 1Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|June 28, 2012
PubMed
まとめ

モリブデンまたはボルンガムのモノアリオキシドピロリド (MAP) 触媒は,ヘキザイソプロピルテルフェノキシド (OHIPT) を使って,高Z選択性の (E,Z,E) -トリエネにホモカップルダイエンを効率的に結合します. 他のMAP触媒の効果は低かった.

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