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Updated: May 20, 2026

Automated, High-resolution Mobile Collection System for the Nitrogen Isotopic Analysis of NOx
07:14

Automated, High-resolution Mobile Collection System for the Nitrogen Isotopic Analysis of NOx

Published on: December 20, 2016

化学プロセスにおけるNO2,N2O4,cis-ONO-NO2,trans-ONO-NO2の相互変換の役割に関する第一原理の研究

Wei-Guang Liu1, William A Goddard

  • 1Materials and Process Simulation Center, California Institute of Technology , Pasadena, California 91125, United States.

Journal of the American Chemical Society
|July 12, 2012
PubMed
まとめ

量子力学の研究は,二酸化窒素 (NO2) 二酸化窒素 (NO2) 二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素二酸化窒素 対称なN2O4二酸化物形成は障壁がないが,シス同位体とトランス同位体はエネルギー障壁が異なる.

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Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.