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Updated: May 20, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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1-アズレニルカルベンのトンネルの再配置

Stefan Henkel1, Y-am Huynh, Patrik Neuhaus

  • 1Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum, D-44801 Bochum, Germany.

Journal of the American Chemical Society
|July 18, 2012
PubMed
まとめ

メタステーブルな分子である1-アズレニルカルベンは,量子トンネリングによって再編成されます. デュテリウム置換は,この再配列を完全に阻害し,カルベン化学における重要な運動同位体効果を明らかにします.

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