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Updated: May 20, 2026

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions

Published on: July 17, 2020

マリノピロール生物合成におけるフラボ酵素によって触媒化されたアトロポ選択的N,C-ビピロールホモカップリング

Kazuya Yamanaka1, Katherine S Ryan, Tobias A M Gulder

  • 1Center for Marine Biotechnology and Biomedicine, Scripps Institution of Oceanography, University of California at San Diego, La Jolla, California 92093, United States.

Journal of the American Chemical Society
|July 18, 2012
PubMed
まとめ

研究者らは,1,3-ビピロロール構造を作り出すための最初の酵素システムを発見しました. 2つのフラビン依存ハロゲネーゼが,マリノピロール生物合成におけるこの前例のないホモカップリング反応を触媒として作用することが判明した.

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