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Updated: May 20, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

パラジウム触媒によるダイアステロセレクティブ sp3 C-H 結合活性化における反応性とステレオ選択性の理解:中間的特徴化と計算的研究

Ramesh Giri1, Yu Lan, Peng Liu

  • 1Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

Journal of the American Chemical Society
|July 27, 2012
PubMed
まとめ

この研究は,オクサゾリン誘導基を用いたPd (II) -触媒化C-H結合機能化における高い反応性とダイアステロ選択性を説明しています. 移行状態におけるステリック効果は,これらの重要な有機反応におけるステレオ化学的結果を決定する.

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