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Updated: May 19, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

溶液中の[FeFe]ヒドロゲネーゼモデル複合体の電子構造は,狭帯域放射検出を用いたX線吸収スペクトロスコピーによって明らかにされました

Nils Leidel1, Petko Chernev, Kajsa G V Havelius

  • 1Institut für Experimentalphysik, Freie Universität Berlin, 14195 Berlin, Germany.

Journal of the American Chemical Society
|August 7, 2012
PubMed
まとめ

この研究では,X線スペクトル検査とDFTを用いて, [FeFe]ヒドロゲネーゼ活性サイト複合体のモデルを分析した. 構造の変化とプロトネーションが電子構成にどのように影響するかを明らかにし,改良されたヒドロゲネーゼ触媒の設計を導く.

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