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Updated: May 19, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

ルイス酸触媒によるムカイヤマアルドール反応におけるダイアステレオ選択性: DFT研究

Joshua M Lee1, Paul Helquist, Olaf Wiest

  • 1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA.

Journal of the American Chemical Society
|August 16, 2012
PubMed
まとめ

密度関数理論は,ルイス酸で触媒化されたムカイヤマ・アルドール反応における代用因子の変化がダイアステレオ選択性にどのように影響するかを明らかにする. 特定の移行構造の形状は,プロ-アンチまたはプロ-シン経路が好まれるかどうかを決定し,メカニズム的理解を助けます.

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Crossed Aldol Reaction Using Strong Bases: Directed Aldol Reaction

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