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Updated: May 19, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
12:30

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

ゴールド・クラスター上のステリカルに要求されるチオラートによる新しい結合モチーフ

Jun-ichi Nishigaki1, Risako Tsunoyama, Hironori Tsunoyama

  • 1Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|August 21, 2012
PubMed
まとめ

研究者は,大量のアレネチオールリガンドを使用して,新しい黄金クラスター,Au(41) ((S-Eind) ((12)) を合成しました. この方法は,従来の黄金クラスター保護戦略とは異なり,金-チオラートオリゴマーの形成を抑制しました.

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